該化工廠在正常生產(chan)過(guo)程中(zhong)會產(chan)生溫度(du)為 20 ~ 50℃、流量為 4 000 ~ 18 000m3/ h 的焦化廢氣,其基本成(cheng)分(fen)及物化數據如表(biao) 1 所(suo)示(shi)。按(an)照國家相(xiang)關廢氣排放標準(zhun)的規定,若要(yao)將有機廢氣凈化達(da)標,需要(yao)由
3 臺蓄熱(re)室組成的大型(xing) RTO 進(jin)行(xing)凈化(hua)。本項目(mu)采用的三室 RTO 是在兩室的基礎上(shang)增加了 1 臺吹掃用蓄熱(re)室,如圖 1 所示(shi)。RTO 正常運行(xing)時,廢氣(qi)(qi)的氣(qi)(qi)和排氣(qi)(qi)通過閥門切換來完成。第1 個工作周期中,廢氣(qi)(qi)
自(zi)下(xia)而(er)上經 A 蓄(xu)熱(re)(re)(re)(re)(re)(re)室(shi)(shi)(shi)(shi)升(sheng)溫(wen),然后進(jin)入(ru)(ru)(ru)燃(ran)燒室(shi)(shi)(shi)(shi)氧(yang)化(hua)放熱(re)(re)(re)(re)(re)(re); 氧(yang)化(hua)放熱(re)(re)(re)(re)(re)(re)結束(shu)后,自(zi)上而(er)下(xia)通過(guo)(guo) B 蓄(xu)熱(re)(re)(re)(re)(re)(re)室(shi)(shi)(shi)(shi),與蓄(xu)熱(re)(re)(re)(re)(re)(re)室(shi)(shi)(shi)(shi)內(nei)的(de)填料(liao)進(jin)行換熱(re)(re)(re)(re)(re)(re),將熱(re)(re)(re)(re)(re)(re)量傳遞給 B 蓄(xu)熱(re)(re)(re)(re)(re)(re)室(shi)(shi)(shi)(shi),再(zai)(zai)經過(guo)(guo)工(gong)藝管(guan)路進(jin)入(ru)(ru)(ru)煙囪(cong)排放; 此(ci)時C 蓄(xu)熱(re)(re)(re)(re)(re)(re)室(shi)(shi)(shi)(shi)處于(yu)吹掃(sao)狀(zhuang)態(tai),用吹掃(sao)風(feng)機將蓄(xu)熱(re)(re)(re)(re)(re)(re)室(shi)(shi)(shi)(shi)( 含(han)集氣(qi)(qi)室(shi)(shi)(shi)(shi)) 中的(de)滯留廢氣(qi)(qi)吹入(ru)(ru)(ru)燃(ran)燒室(shi)(shi)(shi)(shi)氧(yang)化(hua)處理(li),防止因(yin)蓄(xu)熱(re)(re)(re)(re)(re)(re)室(shi)(shi)(shi)(shi)的(de)切(qie)換過(guo)(guo)程(cheng)影響廢氣(qi)(qi)處理(li)效率。第(di) 2 個(ge)工(gong)作(zuo)周期(qi)(qi)中,A 蓄(xu)熱(re)(re)(re)(re)(re)(re)室(shi)(shi)(shi)(shi)處于(yu)吹掃(sao)狀(zhuang)態(tai),廢氣(qi)(qi)自(zi)下(xia)而(er)上進(jin)入(ru)(ru)(ru) B 蓄(xu)熱(re)(re)(re)(re)(re)(re)室(shi)(shi)(shi)(shi),與已吸收熱(re)(re)(re)(re)(re)(re)量的(de)填料(liao)進(jin)行換熱(re)(re)(re)(re)(re)(re)后,進(jin)入(ru)(ru)(ru)燃(ran)燒室(shi)(shi)(shi)(shi)氧(yang)化(hua)放熱(re)(re)(re)(re)(re)(re),再(zai)(zai)自(zi)上而(er)下(xia)通過(guo)(guo)C 蓄(xu)熱(re)(re)(re)(re)(re)(re)室(shi)(shi)(shi)(shi),并(bing)將熱(re)(re)(re)(re)(re)(re)量傳遞給 C 蓄(xu)熱(re)(re)(re)(re)(re)(re)室(shi)(shi)(shi)(shi)后,進(jin)入(ru)(ru)(ru)煙囪(cong)。第(di) 3個(ge)工(gong)作(zuo)周期(qi)(qi)中,B 蓄(xu)熱(re)(re)(re)(re)(re)(re)室(shi)(shi)(shi)(shi)處于(yu)吹掃(sao)狀(zhuang)態(tai),廢氣(qi)(qi)由 C 蓄(xu)熱(re)(re)(re)(re)(re)(re)室(shi)(shi)(shi)(shi)進(jin)入(ru)(ru)(ru),氧(yang)化(hua)放熱(re)(re)(re)(re)(re)(re)后,通過(guo)(guo) A 蓄(xu)熱(re)(re)(re)(re)(re)(re)室(shi)(shi)(shi)(shi)進(jin)入(ru)(ru)(ru)煙囪(cong),完(wan)成了 RTO 裝置(zhi)運(yun)行的(de) 1 個(ge)大周期(qi)(qi),如(ru)此(ci)交替運(yun)行。
本(ben)項目以(yi)能源(yuan)高(gao)效利用為目的,采(cai)用焦爐煤氣(qi)(qi)代(dai)替輔助燃(ran)料,可以(yi)節(jie)約(yue)成(cheng)本(ben),提高(gao)焦爐煤氣(qi)(qi)利用率,同時能夠滿足 RTO 裝置正(zheng)常運(yun)行時的燃(ran)料需求。該裝置主要由(you)燃(ran)燒室(shi)、蓄熱室(shi)( 含(han)集氣(qi)(qi)室(shi)) 及(ji)切換閥門(men)組成(cheng)。
從化產(chan)區域各排(pai)氣洗凈(jing)塔(ta)后(hou)收集的(de)廢(fei)(fei)氣進入(ru)廢(fei)(fei)氣總(zong)管(guan),經(jing)(jing)過安全水封、捕(bu)霧器后(hou)進入(ru)緩沖罐,由廢(fei)(fei)氣引風機(ji)輸送,經(jing)(jing)過阻火器后(hou)進入(ru) RTO 進行焚燒。本項目(mu)中RTO 收集處理(li)的(de)廢(fei)(fei)氣有 14 路(lu),各排(pai)氣洗凈(jing)塔(ta)洗滌
后(hou)的(de)廢(fei)(fei)(fei)氣(qi)(qi)(qi)通(tong)過(guo)各自(zi)(zi)(zi)(zi)的(de)調(diao)節閥(fa)(fa)控制排出壓(ya)力,保(bao)證廢(fei)(fei)(fei)氣(qi)(qi)(qi)進(jin)(jin)(jin)(jin)入(ru)廢(fei)(fei)(fei)氣(qi)(qi)(qi)總管。RTO 冷(leng)態(tai)啟(qi)(qi)動(dong)(dong)(dong)后(hou),首先(xian)啟(qi)(qi)動(dong)(dong)(dong)吹掃(sao)風機(ji),用新(xin)(xin)鮮空氣(qi)(qi)(qi)對設備進(jin)(jin)(jin)(jin)行(xing)(xing)(xing)吹掃(sao); 吹掃(sao)結(jie)(jie)(jie)(jie)束(shu)后(hou),燃(ran)(ran)燒(shao)(shao)系(xi)(xi)統(tong)進(jin)(jin)(jin)(jin)行(xing)(xing)(xing)燃(ran)(ran)氣(qi)(qi)(qi)檢漏,確保(bao)點火系(xi)(xi)統(tong)安全(quan); 檢漏完成(cheng)后(hou),啟(qi)(qi)動(dong)(dong)(dong)燃(ran)(ran)燒(shao)(shao)器(qi),通(tong)過(guo) 9 個(ge)(ge)閥(fa)(fa)門的(de)周期切(qie)換完成(cheng) 3 個(ge)(ge)填(tian)料(liao)(liao)床(chuang)(chuang)的(de)預(yu)熱; 預(yu)熱結(jie)(jie)(jie)(jie)束(shu)后(hou)焦化(hua)廢(fei)(fei)(fei)氣(qi)(qi)(qi)進(jin)(jin)(jin)(jin)入(ru)RTO進(jin)(jin)(jin)(jin)行(xing)(xing)(xing)焚燒(shao)(shao),燃(ran)(ran)燒(shao)(shao)室溫(wen)(wen)度(du)(du)開始(shi)緩慢提(ti)升。如果燃(ran)(ran)燒(shao)(shao)室溫(wen)(wen)度(du)(du)持續上(shang)升,說(shuo)明(ming)廢(fei)(fei)(fei)氣(qi)(qi)(qi)濃(nong)度(du)(du)過(guo)高(gao),當溫(wen)(wen)度(du)(du)達(da)(da)到 1 100℃ 時(shi),打開高(gao)溫(wen)(wen)排放(fang)閥(fa)(fa),將多余的(de)熱量(liang)直接排放(fang)至煙囪; 當溫(wen)(wen)度(du)(du)達(da)(da)到 1 180℃ 時(shi),系(xi)(xi)統(tong)自(zi)(zi)(zi)(zi)動(dong)(dong)(dong)報警; 當溫(wen)(wen)度(du)(du)達(da)(da)到 1 200℃時(shi),為(wei)了(le)(le)確保(bao) RTO 裝(zhuang)置(zhi)(zhi)(zhi)(zhi)安全(quan),RTO 開啟(qi)(qi)自(zi)(zi)(zi)(zi)動(dong)(dong)(dong)離(li)線程(cheng)序(xu)。RTO 離(li)線時(shi),燃(ran)(ran)燒(shao)(shao)系(xi)(xi)統(tong)熄火,廢(fei)(fei)(fei)氣(qi)(qi)(qi)風機(ji)減(jian)速直至停機(ji),新(xin)(xin)風閥(fa)(fa)打開,引入(ru)小(xiao)風量(liang)新(xin)(xin)鮮空氣(qi)(qi)(qi)進(jin)(jin)(jin)(jin)入(ru)RTO 蓄(xu)熱室,開始(shi) RTO 降溫(wen)(wen)程(cheng)序(xu)。為(wei)了(le)(le)降低高(gao)溫(wen)(wen)閥(fa)(fa)的(de)溫(wen)(wen)度(du)(du),在(zai)高(gao)溫(wen)(wen)閥(fa)(fa)設置(zhi)(zhi)(zhi)(zhi)了(le)(le) 1 套水(shui)冷(leng)系(xi)(xi)統(tong),以確保(bao)高(gao)溫(wen)(wen)閥(fa)(fa)的(de)密封性能,水(shui)冷(leng)系(xi)(xi)統(tong)由軟水(shui)槽(cao)(cao)、軟水(shui)循環泵及軟水(shui)冷(leng)卻器(qi)組(zu)成(cheng),軟水(shui)通(tong)過(guo)浮球(qiu)液(ye)位計(ji)(ji)自(zi)(zi)(zi)(zi)動(dong)(dong)(dong)補(bu)充(chong)到軟水(shui)槽(cao)(cao)中,通(tong)過(guo)軟水(shui)循環泵輸送(song)至高(gao)溫(wen)(wen)閥(fa)(fa),再通(tong)過(guo)軟水(shui)冷(leng)卻器(qi)被(bei)循環水(shui)冷(leng)卻后(hou)回到軟水(shui)槽(cao)(cao)。由于焦化(hua)廢(fei)(fei)(fei)氣(qi)(qi)(qi)中有機(ji)成(cheng)分(fen)的(de)沸點較(jiao)高(gao),易凝結(jie)(jie)(jie)(jie)在(zai)蓄(xu)熱填(tian)料(liao)(liao)底(di)(di)部(bu)(bu),堵塞填(tian)料(liao)(liao)床(chuang)(chuang)層,本項(xiang)目(mu)中 RTO 設置(zhi)(zhi)(zhi)(zhi)了(le)(le) 1 套反燒(shao)(shao)程(cheng)序(xu),當床(chuang)(chuang)層底(di)(di)部(bu)(bu)和(he)(he)(he)頂(ding)部(bu)(bu)的(de)壓(ya)差(cha)達(da)(da)到3k Pa 時(shi),自(zi)(zi)(zi)(zi)動(dong)(dong)(dong)啟(qi)(qi)動(dong)(dong)(dong)反燒(shao)(shao)程(cheng)序(xu),將凝結(jie)(jie)(jie)(jie)在(zai)蓄(xu)熱填(tian)料(liao)(liao)底(di)(di)部(bu)(bu)的(de)膠狀物質氧化(hua),從(cong)而(er)達(da)(da)到對蓄(xu)熱床(chuang)(chuang)層清(qing)理(li)(li)的(de)目(mu)的(de)。反燒(shao)(shao)程(cheng)序(xu)與正常運(yun)(yun)行(xing)(xing)(xing)一樣,只不過(guo)是排氣(qi)(qi)(qi)溫(wen)(wen)度(du)(du)達(da)(da)到 480℃時(shi)再進(jin)(jin)(jin)(jin)行(xing)(xing)(xing)閥(fa)(fa)門切(qie)換。3 個(ge)(ge)床(chuang)(chuang)層底(di)(di)部(bu)(bu)溫(wen)(wen)度(du)(du)依次達(da)(da)到 480℃時(shi),反燒(shao)(shao)程(cheng)序(xu)自(zi)(zi)(zi)(zi)動(dong)(dong)(dong)結(jie)(jie)(jie)(jie)束(shu),反燒(shao)(shao)程(cheng)序(xu)有自(zi)(zi)(zi)(zi)動(dong)(dong)(dong)和(he)(he)(he)手動(dong)(dong)(dong) 2 種方式。手動(dong)(dong)(dong)方式可根(gen)據實(shi)際運(yun)(yun)行(xing)(xing)(xing)情(qing)況,點擊反燒(shao)(shao)按鈕進(jin)(jin)(jin)(jin)行(xing)(xing)(xing)清(qing)理(li)(li)。為(wei)了(le)(le)保(bao)證系(xi)(xi)統(tong)安全(quan),風機(ji)前設置(zhi)(zhi)(zhi)(zhi)了(le)(le) 3 套可燃(ran)(ran)氣(qi)(qi)(qi)體濃(nong)度(du)(du)監測儀(yi),其(qi)中 1 套為(wei)快速反應型,響應時(shi)間小(xiao)于 1s,用于快速連鎖(suo),當廢(fei)(fei)(fei)氣(qi)(qi)(qi)中可燃(ran)(ran)組(zu)分(fen)濃(nong)度(du)(du)達(da)(da)到爆炸下限的(de) 25% 時(shi),系(xi)(xi)統(tong)自(zi)(zi)(zi)(zi)動(dong)(dong)(dong)連鎖(suo)停機(ji)。同(tong)時(shi) RTO設置(zhi)(zhi)(zhi)(zhi)了(le)(le) 2 個(ge)(ge)防(fang)爆門,當爐(lu)內(nei)壓(ya)力達(da)(da)到 11k Pa 時(shi)自(zi)(zi)(zi)(zi)動(dong)(dong)(dong)泄壓(ya)。3RTO 置(zhi)(zhi)(zhi)(zhi)工(gong)藝優化(hua)及運(yun)(yun)行(xing)(xing)(xing)結(jie)(jie)(jie)(jie)果分(fen)析采用 RTO 裝(zhuang)置(zhi)(zhi)(zhi)(zhi)處(chu)理(li)(li)焦化(hua)廢(fei)(fei)(fei)氣(qi)(qi)(qi),優化(hua) RTO 裝(zhuang)置(zhi)(zhi)(zhi)(zhi)的(de)工(gong)藝性能對提(ti)高(gao)有機(ji)廢(fei)(fei)(fei)氣(qi)(qi)(qi)處(chu)理(li)(li)效率(lv),實(shi)現廢(fei)(fei)(fei)氣(qi)(qi)(qi)達(da)(da)標排放(fang)至關重要,本項(xiang)目(mu)在(zai) RTO 工(gong)藝設計(ji)(ji)等(deng)方面做了(le)(le)升級和(he)(he)(he)改進(jin)(jin)(jin)(jin)。
1 采(cai)用(yong)焦爐煤(mei)氣作為(wei)輔助(zhu)(zhu)燃(ran)料(liao)本項目采(cai)用(yong)焦爐煤(mei)氣作為(wei)輔助(zhu)(zhu)燃(ran)料(liao),既節約了成本,又(you)提高(gao)了焦爐煤(mei)氣的利用(yong)率(lv)。從(cong)用(yong)戶(hu)記錄所(suo)得到的輔助(zhu)(zhu)燃(ran)料(liao)使用(yong)量表明,RTO 裝置(zhi)冷啟(qi)動時(shi)所(suo)需(xu)焦爐煤(mei)氣為(wei) 240m3/ h,能夠滿(man)足(zu) RTO 裝置(zhi)正常運行時(shi)的燃(ran)料(liao)需(xu)求。
2 RTO 前端增加安全水封(feng)、捕霧(wu)器(qi)和阻(zu)火(huo)器(qi)水封(feng)的(de)主要作用(yong)是防(fang)止(zhi)高溫回(hui)火(huo),由于(yu)其(qi)安全性能好,可用(yong)在管(guan)道(dao)收集(ji)前端防(fang)止(zhi)回(hui)火(huo); 焦化廢氣(qi)(qi)中(zhong)含(han)有(you)少量的(de)水分,為使進入(ru) RTO 內部的(de)焦化廢氣(qi)(qi)更加潔凈,增加了
捕霧(wu)器(qi)用于氣(qi)液分離; 與此同時,由(you)于廢氣(qi)中含有易燃(ran)氣(qi)體(ti),為(wei)了阻止(zhi)易燃(ran)氣(qi)體(ti)在(zai)RTO內燃(ran)燒時火(huo)焰(yan)傳(chuan)播到整個管(guan)網中,在(zai) RTO 進氣(qi)管(guan)道(dao)前端增加了阻火(huo)器(qi)。
3 高溫閥水(shui)(shui)冷(leng)系(xi)統在大(da)多(duo)數的 RTO 裝(zhuang)置中(zhong),高溫閥主要靠(kao)自然(ran)散熱。考(kao)慮到(dao)發生緊急情(qing)況時(shi)燃燒室的溫度(du)過(guo)高,項目采用循環水(shui)(shui)冷(leng)卻(que)系(xi)統。水(shui)(shui)冷(leng)系(xi)統由(you)軟(ruan)(ruan)水(shui)(shui)槽(cao)、軟(ruan)(ruan)水(shui)(shui)循環泵及軟(ruan)(ruan)水(shui)(shui)冷(leng)卻(que)器(qi)組成,軟(ruan)(ruan)水(shui)(shui)通(tong)(tong)過(guo)浮球液位計自動(dong)補充到(dao)軟(ruan)(ruan)水(shui)(shui)槽(cao)中(zhong),通(tong)(tong)過(guo)軟(ruan)(ruan)水(shui)(shui)循環泵輸送至高溫閥,再(zai)通(tong)(tong)過(guo)軟(ruan)(ruan)水(shui)(shui)冷(leng)卻(que)器(qi)被(bei)循環水(shui)(shui)冷(leng)卻(que)后進(jin)入軟(ruan)(ruan)水(shui)(shui)槽(cao)。
4 經(jing)工藝優(you)化后的(de) RTO 裝置運(yun)行結果分析表(biao)明:1) 通(tong)過多次(ci)抽樣測量,RTO 燃燒(shao)室表(biao)面溫度基本維(wei)持(chi)在(zai) 50 ~ 70℃,滿(man)足最高溫度≤75℃ 的(de)設(she)計要求。2) 燃燒(shao)室溫度始(shi)終(zhong)維(wei)持(chi)在(zai) 850 ~ 1 100℃ ,保證了(le)有機
廢(fei)氣(qi)(qi)(qi)中的(de)(de)有(you)機成分充分氧化(hua)(hua)燃燒。3) 煙(yan)囪平均出口溫度 120℃ ,低于 150℃ 的(de)(de)設計(ji)要(yao)求(qiu)。4) 經當地環保部門多次抽查,經過 RTO 裝(zhuang)置處理的(de)(de)焦(jiao)化(hua)(hua)廢(fei)氣(qi)(qi)(qi)達(da)(da)到(dao) GB 16171—2012《煉焦(jiao)化(hua)(hua)學工業污染(ran)物(wu)排放標準》的(de)(de)要(yao)求(qiu),有(you)機廢(fei)氣(qi)(qi)(qi)的(de)(de)凈化(hua)(hua)率達(da)(da)到(dao)了(le) 99% ,CO 的(de)(de)凈化(hua)(hua)率達(da)(da)到(dao)了(le) 97% 。
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